Name: Piperidine-2-methylamine
Chemical Formula: C6H14N2
Synonyms: 2-(Aminomethyl)piperidine
CAS Number: 13913-69-8
Recommended Use: Laboratory chemicals, chemical synthesis
Supplier Details: Chemical manufacturer’s information should be listed with address and emergency contact number
Emergency Contact: Refer to supplier's emergency telephone information for immediate assistance
Product Code: Include code if purchasing through a chemical supplier
Identification of Substance: Organic amine derived from piperidine
GHS Classification: Flammable liquid, Acute Toxicity (oral, dermal, inhalation), Eye and Skin Irritant
Signal Word: Danger
Hazard Statements: Harmful if swallowed, toxic in contact with skin, causes serious eye and skin irritation, may cause respiratory irritation
Pictograms: Exclamation mark, health hazard
Precautionary Statements: Avoid breathing vapors, wash thoroughly after handling, wear protective gloves, eye protection, use only outdoors or in well-ventilated areas, keep away from heat, sparks, open flames
Potential Health Effects: Irritation to mucous membranes, dizziness, nausea, respiratory discomfort, headache
NFPA Ratings: Health: 3; Flammability: 2; Reactivity: 0
Chemical Name: Piperidine-2-methylamine
Concentration: 98-100% (pure compound)
Molecular Weight: 114.19 g/mol
Impurities: Limited to trace quantities as determined by certificate of analysis
Regulatory Listings: Hazardous under OSHA criteria
General Advice: Move affected person away from exposure area
Inhalation: Move individual to fresh air immediately, administer artificial respiration if breathing stops, get medical attention
Skin Contact: Remove contaminated clothing, wash affected area thoroughly with soap and water for at least 15 minutes
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present, seek prompt medical evaluation
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical attention
Symptoms: Redness, pain, swelling, trouble breathing, dizziness
Notes to Physician: Symptomatic treatment; monitor for respiratory distress
Suitable Extinguishing Media: Foam, dry chemical, CO2, water spray
Unsuitable Media: Direct water jet due to risk of spreading fire
Hazardous Combustion Products: Toxic nitrogen oxides, carbon monoxide, carbon dioxide
Protective Equipment for Firefighters: Full protective gear, self-contained breathing apparatus
Fire and Explosion Hazards: Vapors can accumulate and ignite, container may burst in heat
Fire Response: Keep containers cool with water, evacuate area, avoid inhaling combustion products
Special Fire Fighting Procedures: Isolate hazard area, keep upwind, prevent runoff from entering waterways
Personal Precautions: Wear gloves, goggles, and appropriate respiratory protection
Environmental Precautions: Prevent chemical from entering soil, waterways, and drains
Containment: Stop leak if safe, use absorbent non-combustible material, collect in suitable container
Spill Cleanup: Ventilate area, remove ignition sources, neutralize residue with dilute acid solution, wash spill site thoroughly
Disposal of Collected Material: Dispose in compliance with local regulations for hazardous materials
Reporting: Report significant releases to local authorities
Handling: Use in well-ventilated space, avoid contact with skin, eyes, and clothing, ground containers when transferring
Precautions: Do not breathe vapors, use only with adequate ventilation, wear chemical-resistant gloves and safety goggles
Safe Storage: Store in tightly closed containers in cool, dry, well-ventilated area away from strong acids, oxidizing agents, and open flames
Storage Temperature: Maintain at room temperature or as recommended by supplier, keep away from incompatible materials
Incompatible Materials: Acid chlorides, strong oxidizers, acids
Advice on Safe Transfer: Use dedicated equipment, clean up any drips or spills without delay
Engineering Controls: Use local exhaust ventilation to minimize vapor concentrations
Permissible Exposure Limit: No OSHA or ACGIH specific value; exposure should be minimized to the lowest practicable level
Respiratory Protection: Chemical cartridge respirator or supplied-air respirator for high concentrations
Eye Protection: Chemical safety goggles or face shield
Hand Protection: Nitrile or neoprene gloves
Skin and Body Protection: Lab coat, chemical-resistant apron, closed-toe shoes
General Hygiene Measures: Wash hands before breaks and after handling the chemical, do not eat, drink, or smoke when handling
Appearance: Colorless to pale yellow liquid
Odor: Amine-like, pungent
Odor Threshold: Not determined
pH: Basic, aqueous solution approx. 11-12
Melting Point: Not well-defined, below room temperature
Boiling Point: 150–160°C at 760 mmHg
Flash Point: 54°C (Closed cup)
Evaporation Rate: Not available
Flammability: Flammable liquid and vapor
Vapor Pressure: Moderately volatile at room temperature
Vapor Density: Heavier than air
Solubility: Miscible in water and organic solvents
Partition Coefficient (log Kow): Not available
Auto-ignition Temperature: Not determined
Decomposition Temperature: Not established
Viscosity: Not available
Chemical Stability: Stable under recommended handling and storage conditions
Reactivity: Reacts with strong oxidizers, acid chlorides, strong acids; may evolve hazardous fumes
Hazardous Reactions: Risk of violent reaction with oxidizing agents
Conditions to Avoid: Exposure to heat, open flames, incompatible materials
Hazardous Decomposition Products: Nitrogen oxides (NOx), carbon monoxide, carbon dioxide when burned
Polymerization: Not expected under normal conditions
Acute Toxicity: Harmful if swallowed, inhaled, or in contact with skin; LD50 (oral, rat): approx. 100–200 mg/kg
Skin Corrosion/Irritation: Causes moderate to severe irritation
Serious Eye Damage/Irritation: Produces severe eye irritation, possible injury
Sensitization: Not classified for skin or respiratory sensitization
Chronic Effects: Prolonged exposure may cause damage to liver or kidneys, central nervous system effects, possible reproductive toxicity
Target Organs: Liver, kidney, CNS
Carcinogenicity: Not classified as carcinogen by major agencies
Mutagenicity: No data suggesting mutagenic impact
Reproductive Toxicity: Data is insufficient for classification
Symptoms of Overexposure: Dizziness, nausea, headache, respiratory tract irritation, dermatitis
Ecotoxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Aquatic Toxicity: Fish LC50 (96h): data unavailable, suspected moderate
Persistence and Degradability: Not readily biodegradable
Bioaccumulative Potential: Low bioaccumulation potential based on structure
Mobility in Soil: Likely to dissipate in moist soil, may contaminate groundwater
Other Adverse Effects: Spills could threaten sewage treatment processes due to toxicity to microorganisms
Product Disposal: Dispose through licensed chemical waste disposal contractor, follow local, regional, and national regulations
Contaminated Packaging: Triple rinse, recycle if possible, otherwise dispose as hazardous waste
Sewage Disposal: Do not discharge to drains or environment
Waste Codes: Use EWC or other relevant hazardous waste code as applicable
Precautions: Prevent exposure of disposal workers, use clearly labeled, closed containers
UN Number: 2733
Proper Shipping Name: Amines, liquid, corrosive, n.o.s. (contains Piperidine-2-methylamine)
Transport Hazard Class: 8 (Corrosive), secondary: 3 (Flammable liquid)
Packing Group: II
Label Requirements: Corrosive, flammable liquid
Marine Pollutant: Not listed as marine pollutant under IMDG
Special Transport Precautions: Secure containers, prevent movement during transit, ensure accurate labeling and documentation, avoid exposure to heat sources during shipping
Transport Regulations: Follow DOT, IATA, IMDG guidelines
OSHA: Classified as a hazardous chemical by OSHA’s Hazard Communication Standard
SARA Title III: Not listed as an extremely hazardous substance
TSCA: Listed in Chemical Substances Inventory
EU REACH: Registered or pre-registered; subject to local workplace labeling and safety rules
Canadian DSL/NDSL: Listed or candidate for assessment
California Proposition 65: Not expected to contain substances known to the state of California to cause cancer or reproductive harm
Other National Information: Always refer to specific country or regional chemical safety requirements for details
Label Elements: Signal word, hazard statements, precautionary statements, pictograms as required
