N-Ethylpyrrole Material Safety Data Sheet (MSDS)

Identification

Product Name: N-Ethylpyrrole
Chemical Family: Heterocyclic organic compound
Synonyms: 1-Ethylpyrrole, Pyrrole, N-ethyl-
CAS Number: 140-55-4
Recommended Use: Reagent, intermediate for organic synthesis, specialty solvent
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Hazard Identification

Classification: Flammable liquid, Acute toxicity (oral, inhalation, dermal), Eye irritation
GHS Label Elements: Flame, Exclamation Mark
Warning: Highly flammable, May irritate skin, eyes, and respiratory tract, Harmful on ingestion and inhalation, Vapors may form explosive mixtures with air
Potential Health Effects: Shortness of breath, headache, dizziness, skin redness or irritation on contact, stomach upset if swallowed, cough or throat irritation from vapors
Environmental Hazards: May be harmful to aquatic life; spills threaten water sources and soil
Physical Hazards: Vapors ignite easily; static discharge risk during handling

Composition / Information on Ingredients

Chemical Name: N-Ethylpyrrole
CAS Number: 140-55-4
Concentration: >99%
Impurities: Trace pyrrole, residual solvents
Additives: None

First Aid Measures

General: Move affected individual to fresh air or safe area; remove contaminated clothing
Inhalation: Remove person to fresh air, loosen tight clothing, seek medical attention if symptoms persist
Skin Contact: Wash skin thoroughly with lots of water and soap, remove any contaminated clothing, seek medical advice for persistent irritation
Eye Contact: Rinse thoroughly with water for at least 15 minutes, lift eyelids; get medical help if discomfort continues
Ingestion: Rinse mouth, do not induce vomiting, never give anything by mouth to an unconscious person; contact a poison center or doctor right away
Important Symptoms: Cough, dizziness, nausea, skin or eye redness
Special Notes for Doctors: Treat symptomatically; monitor for respiratory complications

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, carbon dioxide, foam, alcohol-resistant foam
Unsuitable Media: Water jet
Hazards from Combustion: Toxic and irritating gases (nitrogen oxides, carbon monoxide, carbon dioxide)
Protective Equipment: Full protective gear and self-contained breathing apparatus
Firefighting Procedures: Cool containers with water spray if exposed to fire, keep runoff out of sewers and waterways
Unusual Fire Hazards: Vapors travel and ignite at distant source, containers may rupture under fire conditions

Accidental Release Measures

Personal Precautions: Evacuate nonessential personnel, ventilate area, eliminate ignition sources, wear chemical splash goggles, gloves, and protective clothing
Environmental Precautions: Prevent from entering drains and waterways, contain soil runoff
Containment Methods: Absorb spill onto inert material (sand, earth), collect residue into suitable waste container, keep for disposal
Cleanup Methods: Wash contaminated area with water and detergent, ventilate area thoroughly, dispose waste in accordance with regulations

Handling and Storage

Precautions for Safe Handling: Work in well-ventilated areas, avoid inhalation, prevent skin and eye contact, ground and bond containers and equipment, keep away from sources of ignition, use non-sparking tools, prohibit smoking
Storage Conditions: Store in tightly closed containers under inert gas, in a cool, dry, well-ventilated location, away from heat or sunlight, segregate from strong oxidizers and acids, label clearly, inspect regularly for leaks, avoid storing with flammables and corrosives

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits
Engineering Controls: Local exhaust ventilation, eye wash stations, emergency showers
Personal Protection: Chemical-resistant gloves (nitrile or PVC), safety goggles, long-sleeved clothing, face shield for splash risk
Respiratory Protection: Certified air-purifying respirator during vapor or aerosol exposure
Hygiene Measures: Wash hands and exposed skin after handling, avoid eating and drinking in work areas, change contaminated clothes right away

Physical and Chemical Properties

Appearance: Clear to slightly yellow liquid
Odor: Sweet, characteristic amine-like
Odor Threshold: No data available
pH: Not applicable (non-aqueous)
Melting Point: -70 °C
Boiling Point: 148-150 °C
Flash Point: 38 °C (Closed cup)
Evaporation Rate: No data available
Flammability: Highly flammable
Upper/Lower Explosive Limits: Not precisely defined
Vapor Pressure: Moderate at room temperature
Vapor Density: Heavier than air
Relative Density: 0.97 g/cm³ at 25 °C
Solubility: Miscible with most organic solvents, low solubility in water
Partition Coefficient: Log Pow approx. 1.4
Auto-Ignition Temperature: Approximately 400 °C
Decomposition Temperature: Not specified
Viscosity: Not determined

Stability and Reactivity

Chemical Stability: Stable under standard conditions if kept away from light and air
Incompatible Materials: Strong oxidizers, acids, alkalis, halogens
Hazardous Decomposition: Carbon oxides, nitrogen oxides, toxic organic fumes
Possibility of Hazardous Reactions: Polymerizes on extended contact with air or acids
Conditions to Avoid: Heat, flames, sparks, exposure to moisture or air, contamination with oxidizing agents

Toxicological Information

Acute Toxicity: Oral LD50 (rat): estimated 650 mg/kg; dermal and inhalation toxicity data limited
Skin Corrosion/Irritation: Causes skin irritation
Eye Damage/Irritation: Severe eye irritation on direct contact
Respiratory Irritation: Vapors cause coughing, shortness of breath, and throat discomfort
Chronic Effects: Repeated exposure may affect central nervous system, liver, and kidneys; skin sensitization possible
Carcinogenicity: Not classified as carcinogen by IARC, NTP, or OSHA
Mutagenicity: No data available
Reproductive Toxicity: No conclusive data
Routes of Exposure: Inhalation, ingestion, skin and eye contact
Symptoms: Redness, headache, nausea, dizziness, irritation at high concentrations

Ecological Information

Toxicity to Aquatic Life: Toxic to fish and aquatic invertebrates at low levels
Persistence and Degradability: Readily biodegradable but can bioaccumulate
Bioaccumulation Potential: Moderate (log Pow 1.4)
Mobility in Soil: Moderate; may contaminate groundwater if spilled
Other Adverse Effects: Spills threaten aquatic habitat, disrupt microorganisms, product reacts in environment to form hazardous byproducts
Avoid Release: Keep out of sewers, watercourses, and soil

Disposal Considerations

Disposal Method: Incinerate in chemical incinerator with afterburner and scrubber, collect and dispose of via licensed hazardous chemical waste contractor
Contaminated Packaging: Rinse thoroughly, treat as hazardous waste, do not reuse containers
Special Precautions: Precaution during disposal to avoid vapor exposure, follow federal, state, and local hazardous waste regulations

Transport Information

UN Number: 1993
UN Proper Shipping Name: Flammable liquid, n.o.s. (contains N-Ethylpyrrole)
Transport Hazard Class: 3 (Flammable Liquid)
Packing Group: II
Label Requirements: Flammable Liquid
Special Transport Notes: Avoid temperature extremes during transit, secure upright, comply with regulations for hazardous materials, emergency procedures listed on shipping paperwork

Regulatory Information

OSHA: Flammable liquid under OSHA Hazard Communication Standard
TSCA: Listed in US Toxic Substances Control Act Inventory
SARA Title III: Not listed as an extremely hazardous substance, not subject to section 313 reporting
California Prop 65: Not listed
EINECS: 205-414-5
WHMIS: Class B2 Flammable liquid; D2B, toxic material causing other toxic effects
Other Regulations: Always check local requirements for use, transport, and disposal restrictions