MSDS for 4-Piperidinylcarboxylate

Identification

Product Name: 4-Piperidinylcarboxylate
Chemical Family: Piperidine derivatives
CAS Number: Not assigned; refer to supplier documentation
Synonyms: Piperidine-4-carboxylic acid ester
Recommended Use: Laboratory research only
Supplier Information: Manufacturer’s address, emergency phone number, contact person details
Restrictions on Use: Not for human or veterinary therapeutic applications, not for food or household use

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal), skin corrosion/irritation, serious eye damage/irritation, specific target organ toxicity
Label Elements: Signal word: Danger; Hazard pictograms: exclamation mark, corrosion
Hazard Statements: Causes skin and eye irritation, may be harmful if swallowed or inhaled, may affect central nervous system
Precautionary Statements: Avoid inhalation, use personal protective gear, wash exposed skin thoroughly after handling, do not eat/drink/smoke during use
Potential Health Effects: Irritation to eyes, skin, respiratory tract, headache, dizziness possible on exposure

Composition / Information on Ingredients

Chemical Name: 4-Piperidinylcarboxylate
Concentration: ≥ 98% (high purity grade)
Impurities: Minor piperidinic impurities, not expected to alter hazard profile
Other Ingredients: None reported
Formula: C6H11NO2 (if methyl ester); structure must be verified against specific compound variant

First Aid Measures

Eye Contact: Rinse gently with water for 15 minutes, remove contact lenses if present and easy to do, seek medical attention if irritation persists
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing and shoes, medical assistance needed if inflammation or large area exposure
Inhalation: Move to fresh air immediately, assist breathing as necessary, medical attention required if symptoms (coughing, dizziness) develop
Ingestion: Rinse mouth, seek immediate medical guidance, do not force vomiting unless advised by healthcare professional
Most Important Symptoms/Effects: Burning or stinging sensations, respiratory discomfort, central nervous system effects over time

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry powder, carbon dioxide or foam, use what works for surrounding materials
Specific Hazards: Combustion may generate toxic fumes including nitrogen oxides, carbon monoxide and carbon dioxide
Firefighter Protection: Wear full protective equipment, self-contained breathing apparatus
Special Procedures: Cool exposed containers, evacuate area if needed, avoid breathing vapors

Accidental Release Measures

Personal Precautions: Use protective gloves, goggles, lab coat, prevent skin and eye contact
Environmental Precautions: Prevent runoff into drains, soil, surface waters
Containment and Cleaning: Collect spill with inert absorbent, place in suitable waste container, ventilate area after cleanup
Decontamination: Use dilute sodium hypochlorite or soap and water on affected surfaces

Handling and Storage

Handling Practices: Use chemical fume hood, minimize contact, keep away from open flames or sources of static electricity
Storage Requirements: Keep container tightly closed, store in a dry, cool, well-ventilated place, avoid incompatible substances like strong oxidizers
Special Instructions: Label all containers clearly, stock rotation based on shelf life, avoid prolonged exposure to air and moisture

Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust ventilation, safety shower, emergency eyewash station present in immediate area
Personal Protective Equipment: Lab coat or chemical-resistant apron, gloves (nitrile or equivalent recommended), safety goggles or face shield, NIOSH-approved respirator if airborne concentrations can’t be avoided
Hygiene Measures: No eating or smoking in workspace, wash hands and face after chemical exposure, properly launder contaminated clothing
Occupational Exposure Limits: No established limits; minimize exposure using general chemical safety practices

Physical and Chemical Properties

Appearance: White or off-white powder or crystalline solid
Odor: Faint, amine-like
Melting Point: 50 – 120°C (varies with ester type)
Boiling Point: Decomposes before boiling at standard pressure
Solubility: Slightly soluble in water, soluble in organic solvents such as ethanol and methanol
Vapor Pressure: Low at room temperature
pH: Not applicable in solid state, ranging slightly basic in aqueous solution
Partition Coefficient (n-octanol/water): Not measured specifically
Flash Point: >150°C (closed cup, approximate)
Molecular Weight: Depends on ester group, approx. 129-173 g/mol

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions; sensitive to moisture and heat
Thermal Decomposition: Above 150°C, releases pungent vapors, decomposition products may be hazardous
Incompatible Materials: Strong oxidizing agents, acids, bases, moisture
Hazardous Reactions: None expected if handled correctly; avoid mixing with incompatible chemicals
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide

Toxicological Information

Acute Toxicity: May cause irritation to eyes, mucous membranes, skin; ingestion or prolonged skin contact produces central nervous system depression, nausea, dizziness
Chronic Effects: Repeated overexposure can cause kidney or liver effects in animal studies
Carcinogenicity: No data from EPA, NTP, ACGIH or IARC
Mutagenicity: No published results, not expected based on structure
Routes of Exposure: Eyes, skin, ingestion, inhalation
Target Organs: Eyes, skin, nervous system

Ecological Information

Persistence and Degradability: Expected to degrade slowly in soil and water, not persistent under aerobic conditions
Bioaccumulation Potential: Low, compound does not bioconcentrate in aquatic organisms based on structure prediction
Aquatic Toxicity: Not measured directly, structurally similar piperidine derivatives show moderate aquatic toxicity
Mobility in Soil: Moderate based on leaching studies of piperidine compounds
Other Adverse Effects: Not believed to contribute to ozone depletion or photochemical smog

Disposal Considerations

Waste Management: Dispose as hazardous organic waste following local, state, and federal rules
Container Handling: Triple rinse containers, puncture, label as hazardous waste for safe disposal
Disposal Methods: Approved chemical incinerator or via licensed hazardous waste contractor
Contaminated Packaging: Treat as hazardous chemical container
Do Not: Pour down the drain, into open environment or trash system

Transport Information

UN Number: Not assigned for this compound
Proper Shipping Name: Chemical, n.o.s. (contains 4-Piperidinylcarboxylate)
Transport Hazard Class: 6.1 (toxic substances, if classified as such by regulator)
Packing Group: III (depending on toxicity data and regulatory assessment)
Transport Labels: Toxic if applicable, handle as laboratory chemical regardless of shipping regulation
Special Precautions During Transport: Prevent leaks, keep upright, avoid temperature extremes

Regulatory Information

Federal Inventories: TSCA status undetermined, not on known scheduled substances lists
OSHA Hazards: Eyes, skin, respiratory tract irritant
SARA Title III: Not specified as a reportable substance
International Inventories: Check registration with EU REACH, China IECSC, Canada DSL for export compliance
Labeling Requirements: Follow laboratory chemical labeling guidelines, GHS-compliant product labeling
Special State Regulations: State hazard communication rules may require additional handling instructions or reporting for laboratory staff