Product Name: 4-Morpholinopiperidine
Chemical Formula: C9H18N2O
Molecular Weight: 170.25 g/mol
CAS Number: 3806-34-6
Synonyms: 4-(Morpholin-4-yl)piperidine, N-(4-Piperidinyl)morpholine
Recommended Use: Research and manufacturing chemical
Supplier: Manufacturer or distributor address and emergency contact details printed clearly on shipping and storage records
Emergency Telephone: Local chemical emergency response number
Restrictions: For use in industrial and laboratory settings only
Classification: Acute toxicity (oral, dermal, inhalation); Serious eye irritation; Specific target organ toxicity
GHS Label: Danger
Hazard Statements: Harmful if swallowed; Causes serious eye irritation; May cause respiratory irritation
Pictograms: Exclamation mark, health hazard
Precautionary Statements: Avoid breathing dust/vapors; Wear protective gloves, clothing, and eye protection; Wash hands thoroughly after handling; Use only in a well-ventilated area
Potential Health Effects: Eye and skin irritation, respiratory discomfort, nausea, headaches, dizziness from exposure
Environmental Hazards: Not classified as hazardous to aquatic environment but spills should be avoided
Chemical Name: 4-Morpholinopiperidine
Concentration: Up to 100% pure unless diluted
Impurities: Minor traces of manufacturing byproducts possible, consult COA for batch-specific details
Stabilizers/Additives: None intentionally added
Other Identifiers: N/A
Eye Contact: Rinse eyes gently with clean, lukewarm water for 15 minutes; seek medical attention if irritation persists
Skin Contact: Remove contaminated clothing; wash exposed area with plenty of water and mild soap
Inhalation: Move to fresh air promptly, monitor breathing, provide artificial respiration if needed; seek medical help for ongoing symptoms
Ingestion: Rinse mouth with water (do not induce vomiting); seek immediate medical attention
Medical Attention: Healthcare providers should be informed of exact chemical exposure, provide symptomatic treatment
Important Symptoms: Redness, burning eyes, sensitized skin, coughing, nausea, dizziness
Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, foam, or water spray
Unsuitable Media: High-pressure water jets may spread fire
Specific Hazards: Toxic and irritating fumes released when burning (nitrogen oxides, carbon monoxide)
Advice for Firefighters: Wear full chemical-resistant suits and self-contained breathing apparatus; avoid generating dust
Fire-Fighting Procedures: Remove chemical containers from fire area if safe; cool containers with water if exposed to flame
Explosion Risk: No specific explosion hazard under normal storage and use
Personal Precautions: Evacuate unprotected personnel; wear personal protective gear including respirators, goggles, gloves, and lab coats
Environmental Precautions: Prevent dusty spills from entering drains, soil, or waterways
Containment: Sweep up with non-sparking tools, prevent further leakage or spillage
Cleanup Methods: Collect material in properly labeled, closed containers for disposal; ventilate area thoroughly
Decontamination: Wash area with plenty of water and detergent once bulk material removed
Reporting: Major spills must be reported according to local regulations
Safe Handling: Avoid breathing vapors, contact with skin, and eyes; use only with adequate ventilation; do not eat, drink, or smoke during handling
Storage Requirements: Keep in tightly sealed original containers; store in a cool, dry, well-ventilated location; protect from light, heat, moisture, and incompatible substances
Incompatibilities: Strong oxidizing agents, acids, acid chlorides, acid anhydrides
Specific Practices: Only trained staff should manage and dispense this material; maintain chemical hygiene practices
Storage Temperature: Recommended room temperature or as specified on container label
Occupational Exposure Limits: No occupational exposure limits established by OSHA, ACGIH, or NIOSH for this compound
Engineering Controls: Chemical fume hood or adequate general exhaust ventilation
Personal Protection: Safety goggles, chemical-resistant gloves, lab coat, and suitable respiratory protection (if ventilation is poor or if airborne concentrations exceed safe levels)
Hygiene Measures: Wash hands and face thoroughly after handling; do not touch face or exposed skin during use
Monitoring: Air monitoring recommended during extensive use
Additional Equipment: Eyewash stations and safety showers available in work area
Appearance: Clear or pale yellow liquid, sometimes powder or crystalline (depending on form supplied)
Odor: Slightly amine-like
pH: Not available
Melting Point: 54-57°C
Boiling Point: Approximately 262°C
Flash Point: 127°C (closed cup, approximate value)
Flammability: Not highly flammable, but burns at elevated temperature
Vapor Pressure: Low at room temperature
Solubility: Soluble in water and common organic solvents such as methanol, ethanol, DMSO
Density: 1.01 g/cm³ at 20°C
Partition Coefficient: log Kow not determined
Auto-ignition Temperature: Not established
Decomposition Temperature: Not determined
Evaporation Rate: Data not available
Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: No hazardous reactivity expected in standard laboratory or industrial conditions
Polymerization: Will not occur opon normal use
Hazardous Decomposition: Produces nitrogen oxides, carbon monoxide, carbon dioxide from thermal breakdown
Conditions to Avoid: Heat, strong acids, oxidizers, light (to prevent degradation), moisture
Incompatible Materials: Strong oxidizing agents, acid chlorides, acid anhydrides
Routes of Exposure: Inhalation, skin, eye, ingestion
Acute Toxicity: Harmful if ingested or inhaled; moderate skin and eye irritant
Symptoms: Redness, pain, burning sensation in eyes or on skin, nausea, coughing, dizziness upon inhalation
LD50 (Oral, rat): Data not fully established, but literature suggests moderate toxicity
Chronic Effects: Extended exposure may affect liver/kidneys, based on related structures
Sensitization: No data on allergic potential; treat as possible skin/respiratory sensitizer
Carcinogenicity: Not listed by IARC, NTP, or OSHA as a carcinogen
Mutagenicity/Teratogenicity: Not fully tested; use standard lab caution
Medical Conditions Aggravated: Asthma, skin disorders, liver and kidney conditions
Ecotoxicity: No detailed aquatic studies; can be hazardous in concentrated spills
Persistence/Degradability: Likely biodegradable over time, specific data lacking
Bioaccumulation: Unknown, predicted low risk due to high solubility
Mobility in Soil: Mobile if released due to solubility, may leach to groundwater
Other Effects: Significant spills may change pH of water, harmful to aquatic organisms due to amine nature
Avoid Release: Always prevent entry to soil, waterways, and sewers
Waste Disposal: Collect all waste in properly labeled hazardous waste containers; dispose of through licensed chemical waste contractors
Container Disposal: Decontaminate, triple rinse, and puncture before trash or recycling; follow facility protocol
Sewage Disposal: Do not discharge to drains or water systems
Additional Notes: All disposal should comply with federal, local, and state regulations
Incineration: Suitable for specialized chemical incinerators equipped to scrub nitrogen oxides
UN Number: Not assigned for typical quantities
Proper Shipping Name: Laboratory chemical, not classified as dangerous for transport according to IATA/IMDG/ADR under limited quantity
Hazard Class: Not regulated under current transport codes; check if larger shipments require declaration
Packing Group: Not assigned
Environmental Hazards: Avoid bulk quantities entering water or natural environments
Transport Precautions: Secure packaging, prevent leaks/spills, clearly mark containers
TSCA: Listed for chemical use within the United States
REACH Status: Not registered for commercial use in Europe
Other Regulations: Not a controlled substance under US DEA; laboratory and industrial use only
SARA Title III: Not subject to reporting under Section 302, 304, or 313
California Proposition 65: Not listed
International Regulations: Varies by local jurisdiction; consult country-specific chemical safety authorities
Labeling: Must carry clear hazard warnings, supplier and hazard pictograms as required in country of use
