Product Name: 4-(1-Oxo-2-Propenyl)-Morpholine
Synonyms: N-Acroleinmorpholine, Morpholine, 4-Acroleinyl
CAS Number: 74135-13-6
Recommended Use: Industrial and laboratory applications
Manufacturer: Provided on request
Emergency Contact: Provided on request
Chemical Formula: C7H11NO2
Molecular Weight: 141.17 g/mol
Hazard Classification: Irritant to skin, eyes, and respiratory system; combustible
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation; may cause respiratory tract irritation; harmful if swallowed or inhaled
Pictograms: Exclamation mark, Health hazard
Precautionary Statements: Avoid contact with skin and eyes, use adequate ventilation, do not breathe dust, vapors, or spray
Routes of Exposure: Inhalation, skin and eye contact, ingestion
Chemical Name: 4-(1-Oxo-2-Propenyl)-Morpholine
Concentration: ≥97%
Impurities: Less than 1% unknown organic impurities; Possible presence of solvents or stabilizers as per supplier
Other Components: Not applicable
Inhalation: Remove to fresh air, keep at rest, seek medical attention if symptoms persist
Skin Contact: Wash with plenty of soap and water, remove contaminated clothing, consult a physician for persistent irritation
Eye Contact: Rinse cautiously with water for at least 15 minutes, remove contact lenses if present, obtain medical advice
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical assistance
Other Requirements: Provide symptomatic and supportive care
Suitable Extinguishing Media: Dry chemical, CO2, foam, or water spray
Hazardous Combustion Products: Carbon oxides, nitrogen oxides, toxic fumes
Protective Equipment for Firefighters: Self-contained breathing apparatus, chemical protective clothing
Specific Fire Hazards: Vapors may form explosive mixtures with air, containers may explode in heat of fire
Additional Information: Move containers from fire area if it can be done without risk
Personal Precautions: Evacuate area, provide adequate ventilation, avoid breathing vapors, wear personal protective equipment
Spill Cleanup Methods: Absorb with inert material (e.g. dry sand, earth), collect in suitable container for disposal
Environmental Precautions: Prevent from entering drains, surface water, or soil
Decontamination: Wash spill area with soap and water after material pick-up
Special Instructions: Dispose of contaminated material according to local regulations
Handling: Wear suitable personal protective equipment, use with proper ventilation, avoid splashing, minimize dust and vapor formation
Storage: Keep container tightly closed in a cool, dry, and well-ventilated place, store away from incompatible materials such as oxidizers and strong acids
Incompatibilities: Avoid storage with strong oxidizing agents, acids, and bases
Other Handling Information: Do not eat, drink, or smoke when using this product, wash hands thoroughly after handling
Engineering Controls: Work in a chemical fume hood or well-ventilated area, use closed systems for transfer
Personal Protective Equipment (PPE): Safety goggles, chemical-resistant gloves (nitrile preferred), lab coat, long sleeves
Respiratory Protection: Use a NIOSH-approved respirator for mist/vapor if ventilation is inadequate
Hygiene Measures: Wash hands before eating or drinking, remove contaminated clothing and wash before reuse
Exposure Limits: No occupational exposure limits established; handle as a potentially hazardous substance
Appearance: Clear to pale yellow liquid
Odor: Pungent, characteristic
Odor Threshold: Not available
pH: Not available
Melting Point/Freezing Point: Approximately -30°C
Boiling Point/Range: 230-236°C at 1 atm
Flash Point: 98°C (estimated, closed cup)
Evaporation Rate: Not available
Flammability: Combustible
Vapor Pressure: <1 mmHg at 25°C
Vapor Density: Not determined
Relative Density: 1.10 g/cm3 at 20°C
Solubility: Miscible with water and many organic solvents
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: Not available
Decomposition Temperature: Not available
Viscosity: Not available
Chemical Stability: Stable in recommended storage conditions
Reactivity: Low under normal conditions; reacts with acids, oxidizers
Possibility of Hazardous Reactions: May polymerize with strong acids or bases
Conditions to Avoid: Heat, flames, sparks, incompatible chemicals
Incompatible Materials: Strong oxidizers, strong acids, strong bases
Hazardous Decomposition Products: Produces carbon oxides, nitrogen oxides under fire conditions
Acute Toxicity: Data not fully established; similar morpholine derivatives show oral LD50 in rats between 1500-3000 mg/kg
Skin Corrosion/Irritation: Expected to cause irritation with redness, pain, possible burns on prolonged contact
Serious Eye Damage/Irritation: Expected to be irritating with risk of transient conjunctival injury
Respiratory Sensitization: Prolonged inhalation may cause coughing or breathing difficulty
Skin Sensitization: Not established; possible irritation with repeated exposure
Carcinogenicity: No reliable data available; not on NTP, IARC, or OSHA carcinogen lists
Germ Cell Mutagenicity: No data available
Reproductive Toxicity: No data available
STOT-Single Exposure: Possible drowsiness, dizziness, or respiratory tract irritation
STOT-Repeated Exposure: Not established
Aspiration Hazard: May cause lung damage if ingested and aspirated
Other Health Effects: Similar effects as acrolein and morpholine derivatives
Ecotoxicity: Data not available for target substance; based on structure, expected to be toxic to aquatic organisms in high concentrations
Persistence & Degradability: Expected to be biodegradable under environmental conditions based on similar compounds
Bioaccumulative Potential: No significant bioaccumulation anticipated
Mobility in Soil: High mobility due to solubility in water
Other Adverse Effects: Large spills could temporarily affect aquatic ecosystems by depleting dissolved oxygen
Waste Disposal Methods: Dispose of in accordance with national and local regulations; incineration preferred for hazardous chemical waste
Contaminated Packaging: Rinse with suitable solvent and dispose of as hazardous waste
Disposal Precautions: Keep out of sewers, surface waters, and soil. Follow chemical waste management protocols
Other Notes: Do not dispose of with household garbage or by pouring into drains
UN Number: Not assigned
UN Proper Shipping Name: Not regulated for ground, air, or sea transport under most conditions
Transport Hazard Class: Not classified under ADR/RID, IMDG, IATA
Packing Group: Not classified
Environmental Hazards: Not considered marine pollutant
Special Precautions for User: Handle with care to prevent leakage or spillage, utilize secondary containment during transport
TSCA Status: Listed or exempt
REACH Status: Not specifically registered
OSHA Status: Hazardous chemical as defined under OSHA Hazard Communication Standard
SARA Title III: Not listed under Sections 302, 304, 313
DSL/NDSL (Canada): Verification required prior to import
California Proposition 65: Not listed
Other National Regulations: May apply pending local jurisdiction review
