MSDS for 3-Morpholinopropylamine

Identification

Product Name: 3-Morpholinopropylamine
Other Names: 1-(3-Aminopropyl)morpholine, 3-(Morpholin-4-yl)propan-1-amine
CAS Number: 2038-03-1
Recommended Use: Intermediate for chemical manufacturing, epoxy curing agents, corrosion inhibitors
Supplier: Manufacturer or distributor contact details required
Emergency Phone Number: National poison center or company emergency contact

Hazard Identification

Classification: Corrosive to skin and eyes, hazardous to aquatic life, harmful if inhaled
GHS Label Elements: Danger
Hazard Statements: Causes severe skin burns and serious eye damage, harmful if swallowed, toxic to aquatic organisms with long-lasting effects
Signal Word: Danger
Pictograms: Corrosive, exclamation mark
Precautionary Statements: Avoid contact with skin and eyes, wear protective equipment, wash thoroughly after handling, avoid release to the environment, store locked up

Composition / Information on Ingredients

Chemical Name: 3-Morpholinopropylamine
Synonym: 1-(3-Aminopropyl)morpholine
CAS Number: 2038-03-1
Percentage: Typically 98–100% purity
Impurities: Low levels of other morpholine derivatives

First Aid Measures

Inhalation: Move to fresh air immediately, seek medical attention if breathing difficulty develops
Skin Contact: Remove contaminated clothing, wash with plenty of water for at least 15 minutes, call a doctor
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present, continue rinsing, seek urgent medical help
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical assistance
Symptoms: Burning, irritation, redness, pain, possible delayed effects such as blistering or permanent tissue damage

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam, water spray
Special Hazards: Releases toxic fumes of nitrogen oxides, carbon monoxide, carbon dioxide on combustion
Protective Equipment: Wear full protective clothing and self-contained breathing apparatus
Advice for Firefighters: Approach from upwind, prevent runoff from fire control from entering water supplies

Accidental Release Measures

Personal Precautions: Wear gloves, impermeable clothing, safety goggles, proper respiratory protection
Environmental Precautions: Avoid spillage into drains, sewers, or watercourses, notify authorities if large quantities enter the environment
Methods for Cleaning Up: Absorb with inert material such as dry sand or earth, collect and place in designated containers for disposal, ventilate area well, wash spill site after material pickup is complete

Handling and Storage

Precautions for Safe Handling: Use only in well-ventilated areas, avoid breathing vapors, prevent skin and eye contact, wash hands thoroughly after handling
Conditions for Safe Storage: Store in tightly closed containers, keep away from heat, sparks, open flame, incompatible substances such as oxidizers and acids, secure in a cool, dry, well-ventilated area
Incompatible Materials: Acids, strong oxidizers, strong bases

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established ACGIH or OSHA limits, but minimize exposure
Engineering Controls: Use fume hood or local exhaust ventilation
Personal Protective Equipment: Nitrile or neoprene gloves, chemical safety goggles, lab coat or apron, suitable respiratory protection if airborne levels are high
Hygiene Measures: Keep away from food and beverages, do not eat, drink, or smoke while using, wash hands before breaks and at end of workday

Physical and Chemical Properties

Appearance: Colorless to slightly yellow liquid
Odor: Ammoniacal, fishy odor
Odor Threshold: Not available
pH: Strongly basic
Melting Point: -32°C
Boiling Point: 228°C
Flash Point: 120°C (closed cup)
Evaporation Rate: Not determined
Flammability: Combustible under certain conditions
Upper/Lower Flammability Limits: Not determined
Vapor Pressure: Low at ambient temperature
Vapor Density: Heavier than air
Relative Density: 0.97–1.00 g/cm³
Solubility: Miscible with water
Partition Coefficient: Not determined
Auto-Ignition Temperature: Not available
Decomposition Temperature: Not available
Viscosity: Not available

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Possibility of Hazardous Reactions: Reacts with acids and strong oxidizing agents
Conditions to Avoid: Heat, flames, ignition sources, incompatibles
Incompatible Materials: Acids, oxidizing agents, strong bases
Hazardous Decomposition Products: Nitrogen oxides, carbon oxides, ammonia fumes

Toxicological Information

Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Toxicity: May cause severe irritation or burns to skin and eyes, harmful if inhaled or ingested
Chronic Effects: Prolonged or repeated exposure may cause dermatitis, respiratory tract irritation
LD50 (oral, rat): 249 mg/kg
Possible Symptoms: Coughing, chest pain, skin redness, deep tissue burns, conjunctivitis
Carcinogenicity: Not classified as a carcinogen by IARC, NTP, or OSHA
Mutagenicity: No data available
Reproductive Toxicity: No data available

Ecological Information

Ecotoxicity: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Degrades slowly in the environment, not readily biodegradable
Bioaccumulative Potential: Low, but avoid release
Mobility in Soil: Highly mobile in water, could contaminate groundwater
Other Adverse Effects: Prevent spillage or leakage into water bodies or soil

Disposal Considerations

Waste Treatment Methods: Dispose of contents and container in accordance with local, regional, national, and international regulations
Do Not: Discharge into drains, land, or waterways
Recommended Disposal: Incineration or chemical treatment in compliance with environmental regulations
Empty Container Handling: Containers must be triple rinsed before disposal, consult waste management authority

Transport Information

UN Number: UN2735
UN Proper Shipping Name: Amines, liquid, corrosive, n.o.s. (3-Morpholinopropylamine)
Transport Hazard Class(es): 8 (corrosive substances)
Packing Group: II
Environmental Hazards: Marine pollutant
Transport Labels: Corrosive symbol, marine pollutant (if applicable)
Special Precautions for Users: Ensure packaging is secure and undamaged, check compatibility before loading, emergency response guide required in vehicle

Regulatory Information

TSCA Status: Listed on the Toxic Substances Control Act Inventory
EINECS Number: 217-817-6
REACH Status: Registered substance in accordance with EU regulations
OSHA: Classified as hazardous
SARA Title III: Not listed as a reportable quantity, but subject to general notification requirements
WHMIS (Canada): Class E, Corrosive Material
Other Regulations: Users must comply with all applicable regional and national chemical safety regulations