Product Name: 3-Ketomorpholine
Chemical Family: Ketones, Heterocyclic Amines
CAS Number: [Provide actual CAS if known]
Synonyms: Morpholine-3-one, 3-Morpholinone
Recommended Use: Intermediate in chemical synthesis, research applications
Manufacturer: [Include manufacturer details]
Contact Information: [Phone, email, address for responsible party]
Emergency Phone: [Insert emergency number specific for chemical spill or exposure]
GHS Classification: Skin corrosion/irritation: Category 2, Eye damage/irritation: Category 2A, Acute toxicity: Category 4
Warning Pictograms: Exclamation mark
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, may be harmful if swallowed, inhaled, or absorbed through skin
Precautionary Statements: Avoid breathing dust, wash hands thoroughly after handling, use only outdoors or in a well-ventilated area, wear protective gear
Potential Health Effects: Prolonged skin contact may result in dermatitis, eye exposure can cause redness/pain, repeated inhalation may lead to respiratory discomfort
Chemical Name: 3-Ketomorpholine
Concentration: 94–100%
Impurities: Less than 2% (specifics depending on batch)
Additives: None intentionally added
Molecular Formula: C4H7NO2
Molecular Weight: 101.11 g/mol
Inhalation: Move to fresh air immediately, seek medical attention for any breathing trouble or persistent cough
Skin Contact: Remove any contaminated clothing, wash thoroughly with soap and water, watch for irritation or any sign of rash
Eye Contact: Rinse eyes with water for several minutes, remove contact lenses, continue washing, consult a healthcare provider
Ingestion: Rinse mouth with plenty of water, call Poison Control or medical help, do not induce vomiting except by medical instruction
Most Important Symptoms: Burning, redness, inflammation of skin or eye tissues, difficulty breathing if dust inhaled
Immediate Medical Attention: If difficulty in breathing, persistent eye irritation, or skin reaction develops, get medical help promptly
Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical, or carbon dioxide
Unsuitable Extinguishing Media: Avoid high-pressure water jets
Hazardous Combustion Products: Carbon oxides (CO, CO2), nitrogen oxides, possibly toxic vapors
Advice for Firefighters: Wear self-contained breathing apparatus and protective clothing, cool containers near fire
Fire Hazards: Dust or fine powder can form explosive mixtures with air, ignite easily
Special Procedures: Isolate hazard area, avoid inhaling fumes, contain fire-fighting effluent to prevent environmental contamination
Personal Precautions: Use protective gear including gloves, safety glasses, dust mask or respirator, minimize skin exposure
Environmental Precautions: Stop further leakage or spillage if safe to do so, prevent release into water sources or soil
Containment: Sweep up material without producing dust, use inert absorbent if necessary
Clean-Up Methods: Place collected material in proper waste container, ventilate area, clean with water after removal
Emergency Procedures: Isolate area, restrict access until clean-up is complete, notify appropriate environmental authorities if contamination risk exists
Handling: Use only in areas with good airflow, avoid dust formation, handle away from sources of sparks or flame, keep container closed when not in use
Storage Conditions: Store in tightly sealed original packaging, keep in dry, cool location away from incompatible materials like oxidizing agents
Incompatible Materials: Strong acids, bases, oxidizers
Technical Measures: Store below 30°C if possible, segregate from food/drink, protect from direct sunlight
Specific End Use: Chemical processing or research purposes only
Occupational Exposure Limits: No specific regulatory limits set, handle as for irritants
Engineering Controls: Local exhaust ventilation, dust extraction systems, use handling enclosures if available
Personal Protective Equipment: Chemical-resistant gloves, splash-proof safety goggles, lab coat or apron, dust mask or respirator (especially during powder handling)
Hygiene Measures: Wash hands before breaks, at end of shift, do not eat, drink, or smoke while handling substance
Environmental Controls: Prevent liquid or powder from reaching drains or open water systems, use spill barriers where needed
Appearance: White to off-white crystalline powder
Odor: Mild, amine-like
Odor Threshold: Not determined
pH: 6–7 (1% solution)
Melting Point: 82–87°C
Boiling Point: Decomposes before boiling
Flash Point: Not determined (solid)
Flammability: Combustible in fine powder/dust forms
Vapor Pressure: Negligible at ambient conditions
Solubility: Soluble in water
Auto-Ignition Temperature: Not available
Partition Coefficient (n-octanol/water): Not available
Decomposition Temperature: Above 120°C
Viscosity: Not applicable (solid)
Chemical Stability: Stable under recommended handling and storage
Reactivity: No dangerous reactions under normal conditions
Possibility of Hazardous Reactions: Risk of dust explosion in air, may react with strong oxidants or bases
Conditions to Avoid: Moisture, high temperatures, ignition sources, open flames
Incompatible Materials: Strong acids, oxidizing agents, alkali metals
Hazardous Decomposition Products: Ammonia, carbon monoxide, carbon dioxide, nitrogen oxides during fire or thermal decomposition
Likely Routes of Exposure: Skin and eye contact, inhalation, ingestion
Acute Toxicity: Data on LD50/LC50 not widely available; moderate toxicity suspected based on related compounds
Skin Corrosion/Irritation: Causes moderate skin irritation, redness, possible burn on prolonged exposure
Serious Eye Damage/Irritation: Causes eye irritation, possible eye damage if not rinsed promptly
Respiratory or Skin Sensitization: Not classified as a sensitizer, but respiratory irritation possible if dust is inhaled
Germ Cell Mutagenicity: No data available
Carcinogenicity: Data not sufficient for classification
Reproductive Toxicity: No specific research available
Effects of Chronic Exposure: Prolonged contact may cause dermatitis, chronic cough, or respiratory discomfort
Synergistic Effects: None reported
Toxicity: No measured LC50 or EC50 data for aquatic or terrestrial life, expected to be moderately hazardous in large quantities
Persistence and Degradability: Not rapidly biodegradable, slow breakdown in environment suspected based on similar morpholine compounds
Bioaccumulative Potential: Unlikely to accumulate in living organisms due to water solubility
Mobility in Soil: Likely mobile if released, can reach groundwater
Other Adverse Effects: Large spills may lower oxygen content in water, kill aquatic plants or fish, long-term exposure can alter microbial soil communities
Precautions: Prevent release into environment, report significant spills to local authorities
Waste Treatment Methods: Use licensed waste disposal contractor, do not pour down drain
Disposal of Product: Incinerate at high temperature in accordance with local, regional, national, and international regulations
Disposal of Packaging: Rinse containers, dispose as chemical waste, avoid reuse of contaminated packaging
Precautions: Avoid environmental contamination, label waste containers clearly
Regulatory Requirements: Comply with all disposal regulations for hazardous chemical waste
UN Number: Not classified under UN regulations for transport as dangerous good
Transport Hazard Class: Not regulated
Packing Group: Not applicable
Special Transport Precautions: Keep container sealed, avoid physical damage, separate from incompatible substances
Environmental Hazards: Not classified, though large spills during transport should be avoided
Transport Labels: Use standard shipping description for chemicals
ADR/RID/IMDG/IATA: Not listed as dangerous good, ensure good practice for chemical transport
Regulatory Status: Not listed on major chemical control lists, no specific exposure limits
Labelling Requirements: Apply GHS hazard pictograms and warnings as detailed above
Safety, Health and Environmental Regulations/Legislation: Observe all applicable workplace, fire, personal protection, transport, and environmental laws
REACH Registration: Not pre-registered or registered due to use as research chemical
Other Regulations: Keep up to date with latest national and regional rules for chemical research and development
Inventory Listings: Not present on US TSCA, EU EINECS, or Japanese ENCS based on current data
Training Advice: Ensure users are trained in handling hazardous laboratory chemicals, emergency procedures, and disposal
